Advanced Organic Chemistry

Author: Francis A. Carey
Publisher: Springer Science & Business Media
ISBN: 1461397952
Format: PDF, ePub
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The purpose of this edition, like that of the earlier ones, is to provide the basis for a deeper understanding of the structures of organic compounds and the mechanisms of organic reactions. The level is aimed at advanced undergraduates and beginning graduate students. Our goals are to solidify the student's understanding of basic concepts provided by an introduction to organic chemistry and to present more information and detail, including quantitative information, than can be presented in the first course in organic chemistry. The first three chapters consider the fundamental topi~s of bonding theory, stereochemistry, and conformation. Chapter 4 discusses the techniques that are used to study and characterize reaction mechanisms. Chapter 9 focuses on aromaticity and the structural basis of aromatic stabilization. The remaining chapters consider basic reaction types, including substituent effects and stereochemistry. As compared to the earlier editions, there has been a modest degree of reorganization. The emergence of free-radical reactions in synthesis has led to the inclusion of certain aspects of free-radical chemistry in Part B. The revised chapter, Chapter 12, empha sizes the distinctive mechanistic and kinetic aspects of free-radical reactions. The synthetic applications will be considered in Part B. We have also split the topics of aromaticity and the reactions of aromatic compounds into two separate chapters, Chapters 9 and 10. This may facilitate use of Chapter 9, which deals with the nature of aromaticity, at an earlier stage if an instructor so desires.

Advanced Organic Chemistry

Author: Francis A. Carey
Publisher: Springer Science & Business Media
ISBN: 9780387683546
Format: PDF, ePub, Docs
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The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part B describes the most general and useful synthetic reactions, organized on the basis of reaction type. It can stand-alone; together, with Part A: Structure and Mechanisms, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for students and exercise solutions for instructors.

Advanced organic chemistry

Author: Jerry March
Publisher: John Wiley & Sons
ISBN:
Format: PDF, ePub, Docs
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After four editions, it2s still the reference students and professionals count on. Advanced Organic Chemistry Fourth Edition Only one reference has brought consistently incisive, up-to date, and comprehensive coverage of the most useful reactions in organic chemistry directly to the fingertips of both students and professionals: Advanced Organic Chemistry. Organized by reaction type, a feature that makes clear the basic principles underlying the nearly 580 reactions described, Advanced Organic Chemistry offers instant access to each reaction2s scope, limitations, and mechanisms. Balancing timely detail and informative breadth, this new updated Fourth Edition: Describes the structure of organic compounds, including chemical bonding and stereochemistry Reviews general reaction mechanisms, including ordinary reactions and photochemical reactions Includes a survey of reactions, arranged by reaction type and by which bonds are broken and formed Includes IUPAC2s newest system for designating reaction mechanisms Features an index to the methods used for preparing given types of compounds Contains more than 15,000 references-5,000 new to this edition-to original papers

March s Advanced Organic Chemistry

Author: Michael B. Smith
Publisher: Wiley
ISBN: 9780470462591
Format: PDF, Kindle
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The new, revised and updated 7th edition of March’s Advanced Organic Chemistry clearly explains the theories and examples of organic chemistry, providing the most comprehensive resource about organic chemistry available. Readers are guided on planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions. The first five chapters deal with the structure of organic compounds and discuss important organic chemistry bonds, fundamental principles of conformation, and stereochemistry of organic molecules, and reactive intermediates in organic chemistry. Chapters 6 to 9 are concerned with general principles of mechanism in organic chemistry, including acids and bases, photochemistry, sonochemistry and microwave irradiation, and finally the relationship between structure and reactivity. The last 10 chapters cover the nature and the scope of organic reactions and their mechanisms. The 7th edition proves again it is a must-have desktop reference and textbook for every student and professional working in organic chemistry or related fields. Key features of the 7th edition: Every chapter has been updated with the most recent reaction information with references to both the primary and review literature New to the 7th edition: 5,500 references since the last edition, updates / rewrites of the retained sections, and an updated index in Appendix B Contains more than 1650 reactions and 20,000 valuable references to the primary literature Includes appendices on the literature of organic chemistry and the classification of reactions according to the compounds synthesized Guides the reader on planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions. Reviews of the previous edition: "...a favorite general organic chemistry text and an easy-to-use one-volume reference. We are confident that this book will remain a dominant reference and that it will reside on many chemists' personal bookshelves." –Journal of Medicinal Chemistry "Who can hope to be seriously accepted as a member of the organic chemistry community without being in possession of at least one edition of 'March'?" –Chemistry and Industry

Writing Reaction Mechanisms in Organic Chemistry

Author: Audrey Miller
Publisher: Academic Press
ISBN: 9780124967120
Format: PDF, ePub, Docs
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Writing Reaction Mechanisms in Organic Chemistry, Second Edition, is an invaluable guide to charting the movements of atoms and electrons in the reactions of organic molecules. Miller and Solomon illustrate that understanding organic reactions is based on applying general principles rather than the rote memorization of unrelated processes, and, in turn, emphasize that writing mechanisms is a practical method of applying knowledge of previously encountered reactions and reaction conditions to new reactions. Students and research chemists alike will find this book useful in providing a method of organizing and synthesizing an oftentimes overwhelming quantity of information into a set of general principles and guidelines for determining and describing organic reaction mechanisms. * Essential for those students who need to have mechanisms explained in greater detail than most organic chemistry textbooks provide. * Illustrated with hundreds of chemical structures * Extensively rewritten and reorganized to make the presentation and format even easier for students to use * Contains many problem sets and answers to all problems to help students work through general principles and applications * Appendixes have been added to this edition that contain easily referenced information on Lewis structures, symbols for chemical notation, and the relative acidities of common substances

Advanced Organic Chemistry

Author: Reinhard Bruckner
Publisher: Academic Press
ISBN: 9780121381103
Format: PDF, Mobi
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Contents - Radical Substitution Reactions at the Saturated C Atom. Nucleophilic Substitution Reactions at the Saturated C Atom. Additions to the Olefinic C=C Double Bond. Eliminations Substitution Reactions on Aromatic Compounds. Nucleophilic Substitution Reactions (Except Through Enolates) on the Carboxyl Carbon. Additions of Heteroatom Nucleophiles to Heterocumulenes. Additions of Heteroatom Nucleophiles to Carbonyl Compounds and Their Secondary Reactions. Addition of H Nucleophiles and Metal Organyls to Carbonyl Compounds. Reaction of Ylides with Saturated or Unsaturated Carbonyl Compounds. Chemistry of the Alkaline Earth Metal Enolates. Rearrangements. Thermal Cycloadditions. Transition Metal-Mediated Alkenylations, Arylations and Alkynylations. Oxidations and Reductions.

Perspectives on Structure and Mechanism in Organic Chemistry

Author: Felix A. Carroll
Publisher: John Wiley & Sons
ISBN: 1118210883
Format: PDF, Docs
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Helps to develop new perspectives and a deeper understanding of organic chemistry Instructors and students alike have praised Perspectives on Structure and Mechanism in Organic Chemistry because it motivates readers to think about organic chemistry in new and exciting ways. Based on the author's first hand classroom experience, the text uses complementary conceptual models to give new perspectives on the structures and reactions of organic compounds. The first five chapters of the text discuss the structure and bonding of stable molecules and reactive intermediates. These are followed by a chapter exploring the methods that organic chemists use to study reaction mechanisms. The remaining chapters examine different types of acid-base, substitution, addition, elimination, pericyclic, and photochemical reactions. This Second Edition has been thoroughly updated and revised to reflect the latest findings in physical organic chemistry. Moreover, this edition features: New references to the latest primary and review literature More study questions to help readers better understand and apply new concepts in organic chemistry Coverage of new topics, including density functional theory, quantum theory of atoms in molecules, Marcus theory, molecular simulations, effect of solvent on organic reactions, asymmetric induction in nucleophilic additions to carbonyl compounds, and dynamic effects on reaction pathways The nearly 400 problems in the text do more than allow students to test their understanding of the concepts presented in each chapter. They also encourage readers to actively review and evaluate the chemical literature and to develop and defend their own ideas. With its emphasis on complementary models and independent problem-solving, this text is ideal for upper-level undergraduate and graduate courses in organic chemistry.