Chemical Modification Properties and Usage of Lignin

Author: Thomas Q. Hu
Publisher: Springer Science & Business Media
ISBN: 1461506433
Format: PDF, ePub
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One of the most significant challenges facing mankind in the twenty-first century is the development of a sustainable global economy. Within the scientific community, this calls for the development of processes and technologies that will allow the sustainable production of materials from renewable natural resources. Plant material, in particular lignin, is one such resource. During the annual production of about 100 million metric tons of chemical wood pulps worldwide, approximately 45 and 2 million metric tons/year of kraft lignin and lignosulfonates, respectively, are also generated. Although lignosulfonates have found many applications outside the pulp and paper industry, the majority of kraft lignin is being used internally as a low-grade fuel for the kraft pulping operation. A surplus of kraft lignin will become available as kraft mills increase their pulp production without expanding the capacity of their recovery boilers that utilize lignin as a fuel. There is a tremendous opportunity and an enormous economic incentive to find better uses of kraft lignin, lignosulfonates and other industriallignins. The pulp and paper industry not only produces an enormous amount of lignins as by products of chemical wood pulps, but it also utilizes about 10 million metric tons of lignin per year as a component of mechanical wood pulps and papers. Mechanical wood pulps, produced in a yield of 90-98% with the retention of lignin, are mainly used to make low-quality, non-permanent papers such as newsprint and telephone directories because of the light-induced photooxidation of lignin and the yellowing of the papers.

Chemical Modification of Lignocellulosic Materials

Author: DavidN.-S. Hon
Publisher: Routledge
ISBN: 1351461486
Format: PDF, ePub, Mobi
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This volume emphasizes the growing need for wood products with advanced engineering properties. It details the fundamental principles of cellulose technology and presents current techniques to modifying the basic chemistry of lignocellulosic materials. The work: discusses the cost-efficient use of cellulose derivatives in a variety of commodities; highlights the chemical modification of wood by methods such as etherification, esterification and thermoplasticization; considers recent progress in the lignocellulosic liquefaction of wood; and more.

Lignin and Lignans as Renewable Raw Materials

Author: Francisco G. Calvo-Flores
Publisher: John Wiley & Sons
ISBN: 111868351X
Format: PDF, Docs
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As naturally occurring and abundant sources of non-fossil carbon, lignin and lignans offer exciting possibilities as a source of commercially valuable products, moving away from petrochemical-based feedstocks in favour of renewable raw materials. Lignin can be used directly in fields such as agriculture, livestock, soil rehabilitation, bioremediation and the polymer industry, or it can be chemically modified for the fabrication of specialty and high-value chemicals such as resins, adhesives, fuels and greases. Lignin and Lignans as Renewable Raw Materials presents a multidisciplinary overview of the state-of-the-art and future prospects of lignin and lignans. The book discusses the origin, structure, function and applications of both types of compounds, describing the main resources and values of these products as carbon raw materials. Topics covered include: • Structure and physicochemical properties • Lignin detection methods • Biosynthesis of lignin • Isolation methods • Characterization and modification of lignins • Applications of modified and unmodified lignins • Lignans: structure, chemical and biological properties • Future perspectives This book is a comprehensive resource for researchers, scientists and engineers in academia and industry working on new possibilities for the application of renewable raw materials. For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs

Lignin in Polymer Composites

Author: Omar Faruk
Publisher: William Andrew
ISBN: 0323355668
Format: PDF, ePub
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Lignin in Polymer Composites presents the latest information on lignin, a natural polymer derived from renewable resources that has great potential as a reinforcement material in composites because it is non-toxic, inexpensive, available in large amounts, and is starting to be deployed in various materials applications due to its advantages over more traditional oil-based materials. This book reviews the state-of-the-art on the topic and their applications to composites, including thermoplastic, thermosets, rubber, foams, bioplastics, nanocomposites, and lignin-based carbon fiber composites. In addition, the book covers critical assessments on the economics of lignin, including a cost-performance analysis that discusses its strengths and weaknesses as a reinforcement material. Finally, the huge potential applications of lignin in industry are explored with respect to its low cost, recyclable properties, and fully biodegradable composites, and the way they apply to the automotive, construction, and packaging industries. Reviews the state-of-the-art on the topic and their applications to composites, including thermoplastic, thermosets, rubber, foams, bioplastics, nanocomposites, and lignin-based carbon fiber composites Presents the essential processing and properties information for engineers and materials scientists, enabling the use of lignin in composites Provides critical insight into the applications and future trends of lignin-based composites, including advantages, shortcomings, and economics Includes a thorough coverage of extraction, modification, processing, and applications of the material

Monomers Polymers and Composites from Renewable Resources

Author: Mohamed Naceur Belgacem
Publisher: Elsevier
ISBN: 9780080560519
Format: PDF, ePub, Mobi
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The progressive dwindling of fossil resources, coupled with the drastic increase in oil prices, have sparked a feverish activity in search of alternatives based on renewable resources for the production of energy. Given the predominance of petroleum- and carbon-based chemistry for the manufacture of organic chemical commodities, a similar preoccupation has recently generated numerous initiatives aimed at replacing these fossil sources with renewable counterparts. In particular, major efforts are being conducted in the field of polymer science and technology to prepare macromolecular materials based on renewable resources. The concept of the bio-refinery, viz. the rational exploitation of the vegetable biomass in terms of the separation of its components and their utilisation as such, or after suitable chemical modifications, is thus gaining momentum and considerable financial backing from both the public and private sectors. This collection of chapters, each one written by internationally recognised experts in the corresponding field, covers in a comprehensive fashion all the major aspects related to the synthesis, characterization and properties of macromolecular materials prepared using renewable resources as such, or after appropriate modifications. Thus, monomers such as terpenes and furans, oligomers like rosin and tannins, and polymers ranging from cellulose to proteins and including macromolecules synthesized by microbes, are discussed with the purpose of showing the extraordinary variety of materials that can be prepared from their intelligent exploitation. Particular emphasis has been placed on recent advances and imminent perspectives, given the incessantly growing interest that this area is experiencing in both the scientific and technological realms. Discusses bio-refining with explicit application to materials Replete with examples of applications of the concept of sustainable development Presents an impressive variety of novel macromolecular materials

Cereal Straw as a Resource for Sustainable Biomaterials and Biofuels

Author: RunCang Sun
Publisher: Elsevier
ISBN: 9780080932675
Format: PDF, ePub, Mobi
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Materials from renewable resources are receiving increased attention, as leading industries and manufacturers attempt to replace declining petrochemical-based feedstocks with products derived from natural biomass, such as cereal straws. Cereal straws are expected to play an important role in the shift toward a sustainable economy, and a basic knowledge of the composition and structure of cereal straw is the key to using it wisely. Cereal Straw as a Resource for Sustainable Biomaterials and Biofuels: Chemistry, Extractives, Lignins, Hemicelluloses and Cellulose provides an introduction to straw chemistry. Topics discussed include the structure, ultrastructure, and chemical composition of straw; the structure and isolation of extractives from the straw; the three main components of straw: cellulose, hemicelluloses, and lignins; and chemical modifications of straw for industrial applications. This book will be helpful to scientists interested in the areas of natural resource management, environmental chemistry, plant chemistry, material science, polysaccharide chemistry, and lignin chemistry. It will also be of interest to academic and industrial scientists/researchers interested in novel applications of agricultural residues for industrial and/or recycling technologies. Provides the basics of straw composition and the structure of its cell walls Details the procedures required to fractionate straw components to produce chemical derivatives from straw cellulose, hemicelluloses, and lignins Elucidates new techniques for the production of biodegradable materials for the energy sector, chemical industry, and pulp and paper business

Production of Biofuels and Chemicals from Lignin

Author: Zhen Fang
Publisher: Springer
ISBN: 9811019657
Format: PDF
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This book provides state-of-the-art reviews, current research on and the prospects of lignin production, biological, thermal and chemical conversion methods, and lignin technoeconomics. Fundamental topics related to lignin chemistry, properties, analysis, characterization, and depolymerization mechanisms, as well as enzymatic, fungal and bacterial degradation methods are covered. The book also examines practical topics related to technologies for lignin and ultra-pure lignin recovery, activated carbon, carbon fiber production and materials, and addresses the biological conversion of lignin with fungi, bacteria or enzymes to produce chemicals, along with chemical, catalytic, thermochemical and solvolysis conversion methods. Lastly, it presents a case study on practical polyurethane foam production using lignin. Lignin has a bright future and will be an essential feedstock for producing renewable chemicals, biofuels and value-added products. Offering comprehensive information on this promising material, the book represents a valuable resource for students, researchers, academicians and industrialists in the field of biochemistry and energy.

Lignin and Lignans as Renewable Raw Materials

Author: Calvo-flores
Publisher: John Wiley & Sons
ISBN: 1118597869
Format: PDF
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As naturally occurring and abundant sources of non–fossil carbon, lignin and lignans offer exciting possibilities as a source of commercially valuable products, moving away from petrochemical–based feedstocks in favour of renewable raw materials. Lignin can be used directly in fields such as agriculture, livestock, soil rehabilitation, bioremediation and the polymer industry, or it can be chemically modified for the fabrication of specialty and high–value chemicals such as resins, adhesives, fuels and greases. Lignin and Lignans as Renewable Raw Materials presents a multidisciplinary overview of the state–of–the–art and future prospects of lignin and lignans. The book discusses the origin, structure, function and applications of both types of compounds, describing the main resources and values of these products as carbon raw materials. Topics covered include: Structure and physicochemical properties Lignin detection methods Biosynthesis of lignin Isolation methods Characterization and modification of lignins Applications of modified and unmodified lignins Lignans: structure, chemical and biological properties Future perspectives This book is a comprehensive resource for researchers, scientists and engineers in academia and industry working on new possibilities for the application of renewable raw materials. For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs

Methods in Lignin Chemistry

Author: Stephen Y. Lin
Publisher: Springer Science & Business Media
ISBN: 3642740650
Format: PDF, Docs
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An up-to-date compilation of the theoretical background and practical procedures involved in lignin characterization. Whenever possible, the procedures are presented in sufficient detail to enable the reader to perform the analysis solely by following the step-by-step description. The advantages and limitations of individual methods are discussed and, more importantly, illustrated by typical analytical data in comparison to results obtained from other methods. This handbook serves the need of researchers and other professionals in academia, the pulp and paper industry as well as allied industries. It is equally useful for those with no previous experience in lignin or lignocellulosics.

Advances in Biorefineries

Author: Keith W. Waldron
Publisher: Elsevier
ISBN: 0857097385
Format: PDF, ePub, Docs
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Biorefineries are an essential technology in converting biomass into biofuels or other useful materials. Advances in Biorefineries provides a comprehensive overview of biorefining processing techniques and technologies, and the biofuels and other materials produced. Part one focuses on methods of optimizing the biorefining process and assessing its environmental and economic impact. It also looks at current and developing technologies for producing value-added materials. Part two goes on to explore these materials with a focus on biofuels and other value-added products. It considers the properties, limitations, and practical applications of these products and how they can be used to meet the increasing demand for renewable and sustainable fuels as an alternative to fossil fuels. Advances in Biorefineries is a vital reference for biorefinery/process engineers, industrial biochemists/chemists, biomass/waste scientists and researchers and academics in the field. A comprehensive and systematic reference on the advanced biomass recovery and conversion processes used in biorefineries Reviews developments in biorefining processes Discusses the wide range of value-added products from biorefineries, from biofuel to biolubricants and bioadhesives