Rearrangements in Ground and Excited States

Author: Paul de Mayo
Publisher: Academic Press
ISBN: 1483218716
Format: PDF, ePub, Docs
Download Now
Rearrangement in ground and excited states, Volume 1 covers essays on the rearrangements of carbocations; gas-phase ion rearrangements; and rearrangements of carbenes and nitrenes. The book also includes essays on the free-radical rearrangements; hypothetical biradical pathways in thermal unimolecular rearrangements; and rearrangements in carbanions. Chemists and people involved in the study of rearrangements will find the book invaluable.

Carbon 13 NMR Spectroscopy

Author: J Stothers
Publisher: Elsevier
ISBN: 0323145507
Format: PDF, ePub, Docs
Download Now
Carbon-13 NMR Spectroscopy focuses on the potential of 13C techniques and the practical difficulties associated with the detection of 13C NMR absorption. This monograph includes a descriptive presentation of 13C shielding results that has been adopted with emphasis on the structural and stereochemical aspects. Organized into four parts encompassing 11 chapters, this book starts with an overview of the characteristics of the NMR signals derived from compounds containing 13C nuclei in natural abundance that are inherently much weaker than those exhibited by protons. This monograph then compares the primary characteristics of 13C NMR with the more familiar proton methods. Other chapters consider the 13C spectra of pyridine, pyridazine, pyrimidine, pyrazine, s-triazine, and s-tetrazine. The final chapter deals with the effects of solute–solvent interactions on the shieldings of other nuclei. This monograph is intended for organic chemists, graduate students, and researchers in various branches of chemistry with an interest in 13C NMR methods as another approach to chemical problems.

Advances in Electron Transfer Chemistry

Author: P.S. Mariano
Publisher: Elsevier
ISBN: 9780080552675
Format: PDF, ePub
Download Now
It is clear that electron transfer chemisty is now one of the most active areas of chemical study. Advances in Electron Transfer Chemistry has been designed to allow scientists who are developing new knowledge in this rapidly expanding area to describe their most recent research findings. This volume will serve those interested in learning about current breakthroughs in this rapidly expanding area of chemical research.

Pericyclic Reactions

Author: Alan P. Marchand
Publisher: Academic Press
ISBN: 1483218651
Format: PDF, Kindle
Download Now
Pericyclic Reactions,Volume 35-II covers the theoretical approaches to pericyclic reactions and reviews of pericyclic reactions of reactive intermediates and of particular reaction types. The book discusses some of the experimental approaches used to establish the authenticity of an apparent pericyclic reaction; the transient and observable carbocation rearrangements; and orbital symmetry interactions which are “extra stabilizing or destabilizing. The text then describes the pericyclic reactions of cumulenes; the cheletropic reactions; the applications of frontier molecular orbital theory to pericyclic reactions. A general theoretical model accommodating concerted reaction profiles for forbidden thermal reactions is also encompassed. Chemists and people involved in the study of pericyclic reactions will find the book invaluable.

Advanced organic chemistry

Author: Jerry March
Publisher: John Wiley & Sons
ISBN:
Format: PDF
Download Now
After four editions, it2s still the reference students and professionals count on. Advanced Organic Chemistry Fourth Edition Only one reference has brought consistently incisive, up-to date, and comprehensive coverage of the most useful reactions in organic chemistry directly to the fingertips of both students and professionals: Advanced Organic Chemistry. Organized by reaction type, a feature that makes clear the basic principles underlying the nearly 580 reactions described, Advanced Organic Chemistry offers instant access to each reaction2s scope, limitations, and mechanisms. Balancing timely detail and informative breadth, this new updated Fourth Edition: Describes the structure of organic compounds, including chemical bonding and stereochemistry Reviews general reaction mechanisms, including ordinary reactions and photochemical reactions Includes a survey of reactions, arranged by reaction type and by which bonds are broken and formed Includes IUPAC2s newest system for designating reaction mechanisms Features an index to the methods used for preparing given types of compounds Contains more than 15,000 references-5,000 new to this edition-to original papers

March s Advanced Organic Chemistry

Author: Michael B. Smith
Publisher: Wiley-Interscience
ISBN:
Format: PDF, Kindle
Download Now
From the reviews of the Fourth Edition ... "March has been uncompromising in his search for clarity and utility in presentations of a wide variety of essential organic chemistry. It remains an accessible and useful tool for both specialists and nonspecialists in the field. It does an excellent job both as a text for first-year graduate students and a handy reference for others."-Journal of Chemical Education "The ratio of information to price makes this book a wonderful bargain."-American Scientist New to this Fifth Edition: * Michael Smith from the University of Connecticut joins as coauthor for the Fifth Edition * Contains 20,000 valuable, selected references to the primary literature-5,000 new to this edition * 40 entirely new sections covering the most important developments in organic chemistry since the previous edition * Updated illustrations of molecular structures